Cupellation is an oxidizing fusion of an alloy of lead, gold, and silver in an absorbent vessel known as a "cupel"
During cupellation the lead is oxidized to litharge (PbO), most of which is absorbed by the cupel, leaving at the finish a bead of gold, silver, and most of the platinum and associated precious metals that may be present. The bead is subsequently treated to determine its precious-metal content. Cupels are typically made from magnesia MgO (sometimes mistakenly referred to as magnesite), bone ash, portland cement, and other materials. |
The lead button for cupellation is typically generated in the crucible fusion from the fire assay process, but can also be produced by a scorification assay, or a bullion assay where the precious metal is wrapped in lead foil.
Typical cupellation furnace temperatures in gold and silver assays are 1650-1700F, but can vary with technique, air flow volume, and cupel material. |
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